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Updated: Feb 24, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

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アンチアロマティック・シングレット・サイクロペンタディエニル・ズウィテリオンの分離

Paolo Costa1, Iris Trosien1, Joel Mieres-Perez1

  • 1Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum , 44780 Bochum, Germany.

Journal of the American Chemical Society
|August 23, 2017
PubMed
まとめ

研究者はテトラクロロcyclopentadienylideneとボロントリフッ化物 (BF3) から抗芳香型ズウィテリオンを合成した. この不安定な分子は放射線で再編成されますが,効率的な合成のために追加のBF3によって安定させることができます.

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