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Updated: Feb 22, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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銅で触媒化されたチオランアセンブリによる非対称な酸化ヌパールチオアルカロイドの総合成

Jacob J Lacharity1, Jeremy Fournier1, Ping Lu1

  • 1Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.

Journal of the American Chemical Society
|September 16, 2017
PubMed
まとめ

この研究は,黄色い水から2つの二次性セスキーターペンの (+) - 6 - ヒドロキシチオニュファリジンと (-) - 6 - ヒドロキシチオニュフルチンの最初の非対称的全合成を示しています. 独特のチアスピランコアを構築するために新しいスティーブンス再配置戦略が採用されました.

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