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関連する概念動画

Electromotive Force02:36

Electromotive Force

31.3K
Electricity is generated by either electrons or ions flowing through a solution or a conducting medium. This flow of electrons or specifically electrical charge is defined as an electric current. When electrons move through a wire, they generate an electric current. It can be recalled  that in a redox reaction, electrons are lost and gained. In the spontaneous redox reaction of zinc  with copper, when zinc is immersed in a copper ion solution, a transfer of electrons from one substance to...
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Electromotive Force01:02

Electromotive Force

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Electromotive force (emf) is the force that causes current to flow from a higher to a lower  potential. The term "electromotive force" is used for historical reasons, even though emf is not a force at all.
Any circuit with a constant current must contain an emf-producing source. Examples of emf sources include batteries, electric generators, solar cells, thermocouples, and fuel cells. All these sources transform energy of some kind (mechanical, chemical, thermal, and so on)...
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Thomson's e/m Experiment01:19

Thomson's e/m Experiment

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In a beam of charged particles created by a heated cathode, the particles move at different speeds. However, many applications need a beam with uniform particle speeds. An arrangement known as a velocity selector uses electric and magnetic fields to pick particles with a particular speed from the beam.
A particle with charge q, speed v, and mass m enters an area from the top, where the magnetic and electric fields are perpendicular both to the particle's motion and to one another. The magnetic...
7.8K
Carrier Generation and Recombination01:22

Carrier Generation and Recombination

1.6K
Carrier generation is the process by which electron-hole pairs (EHPs) are created within the semiconductor. In direct-bandgap semiconductors, such as gallium arsenide (GaAs), this occurs efficiently when energy absorption prompts valence electrons to leap into the conduction band, leaving behind holes.
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...
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Electrochemical Systems01:24

Electrochemical Systems

130
Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution,...
130
The Electrical Double Layer01:30

The Electrical Double Layer

176
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
176

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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics

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電子輸送連鎖における還元電荷シフト反応の媒介

Maximilian Wolf1, Carmen Villegas2, Olga Trukhina3,4

  • 1Department of Chemistry and Pharmacy & Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg , Egerlandstr. 3, 91058 Erlangen, Germany.

Journal of the American Chemical Society
|October 14, 2017
PubMed
まとめ

研究者は効率的な電荷輸送のための 新種の電子ドナー-受容体結合体を合成した. この戦略は,エネルギー損失を最小限に抑え,単方向の長距離電荷転送を達成するために,フルレンペアとリンクされたポルフィリンまたはフタロシアニンを利用します.

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A Micro-agar Salt Bridge Electrode for Analyzing the Proton Turnover Rate of Recombinant Membrane Proteins
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関連する実験動画

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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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A Micro-agar Salt Bridge Electrode for Analyzing the Proton Turnover Rate of Recombinant Membrane Proteins
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科学分野:

  • 材料科学
  • 写真化学
  • 超分子化学

背景:

  • 協和性ドナー-受容体の結合は,人工光合成と分子電子工学にとって極めて重要です.
  • 効率的な電荷輸送には,電子伝送プロセス中のエネルギー損失を最小限に抑える必要があります.

研究 の 目的:

  • 新しいドナー-受容体1-受容体2結合体を合成し,特徴づけること.
  • これらのシステム内の電荷伝送ダイナミクスとエネルギー伝送メカニズムを調査する.

主な方法:

  • Zn (II) ポルフィリンと Zn (II) フォタロシアニンベースの結合物の合成.
  • 興奮状態のダイナミクスのためのフェムト秒間吸収スペクトロスコーピー.
  • 瞬時の吸収スペクトルの計算分析

主要な成果:

  • 興奮ドナーからフルレンペア (C60とC70) への遠距離単方向の電荷輸送が実証された.
  • 短距離の電荷移転プロセスのカスケードが特定された. 還元電荷移転を含む.
  • 放電器群が電荷移転運動に及ぼす影響

結論:

  • 開発された戦略は,効率的な電荷輸送のための微調整された酸化還元グラデントを効果的に確立します.
  • 弱い電子結合における電荷シフト反応の媒介状態が提案されている.
  • 三重三重のエネルギー伝送と電荷伝送の間の密接な関係が明らかになった.