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Updated: Feb 20, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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Z-またはE-三置換型アリルアルコールとエーサーの合成 動力的に制御されたクロスメタテシスによるRu カテコチオラート複合体

Chaofan Xu1, Zhenxing Liu1, Sebastian Torker1

  • 1Department of Chemistry, Merkert Chemistry Center, Boston College , Chestnut Hill, Massachusetts 02467, United States.

Journal of the American Chemical Society
|October 26, 2017
PubMed
まとめ

この研究は,Z-またはE-三置換アルケンを生成するための最初の運動制御された交叉転移反応を導入する. ルテニウム触媒を用いて,この方法は高いステレオ同位体純度を持つアリルアルコールとエーテルを効率的に生成します.

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