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Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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独特のボリラニル基の生成と構造

John C Walton1, Timothy R McFadden2, Dennis P Curran2

  • 1EaStCHEM School of Chemistry, University of St. Andrews , St. Andrews, Fife KY16 9ST, United Kingdom.

Journal of the American Chemical Society
|November 4, 2017
PubMed
まとめ

3つ組のリングボラサイクロプロパンから派生したボリラニルラジカルは,EPR光譜を用いて初めて検出された. ボロン-水素結合解離エネルギーに関する洞察を提供するために,それらの平面のπ-キャラクターと反応性が特徴付けられました.

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