孤立したコバルト単一原子サイトを持つ空洞のN-ドープされた炭素球:酸素減少のための優れた電解剤
Yunhu Han1, Yang-Gang Wang1, Wenxing Chen1
1Department of Chemistry, Tsinghua University , Beijing 100084, China.
Journal of the American Chemical Society
|November 8, 2017
まとめ
新しいコバルト触媒は,中空の窒素ドーピングされた炭素球 (ISAS-Co/HNCS) に単一の原子サイトを分離し,酸性媒体における酸素還元反応 (ORR) の高効率を示し,プラチナ性能に近づいています.
科学分野:
- 電気化学
- 材料科学
- カタリシス
背景:
- 酸素還元反応 (ORR) はエネルギー変換装置にとって極めて重要です.
- プラチナ基の触媒は 効果は高いが 希少である
- 酸性媒体でのORRのための非貴金属触媒の開発は大きな課題です.
研究 の 目的:
- 酸素還元反応 (ORR) のための低コストで超安定で高効率の非貴金属触媒を開発する.
- Nドーピングされた空洞の炭素球に固定された単一の原子の場所を持つ新しい触媒を調査する.
- テンプレートアシスタド・パイロリシス (TAP) メソッドの触媒合成の可能性を調査する.
主な方法:
- テンプレート・アシスト・パイロリシス (TAP) 方法
- 触媒の構造と組成の特徴
- 酸性環境における触媒のORR性能の電気化学的試験
- 触媒メカニズムを理解するための密度関数理論 (DFT) の計算.
主要な成果:
- 空洞のNドーピングされた炭素球 (ISAS-Co/HNCS) に固定された単一の原子サイトを隔離したユニークなコバルト触媒が成功して合成されました.
- ISAS-Co/HNCS触媒は,Pt/Cに近い半波電位で,酸性環境で優れたORR性能を示した.
- 実験とDFT計算は,孤立したCoサイトがOH*水素化を強化することによって高いORR活動に責任を負うことを確認した.
結論:
- 開発されたTAP方法は,高度なORR触媒を作るのに有効です.
- 空洞のNドーピングされた炭素球の単一の原子サイトは,高性能で低コストのORR電触媒のための有望な戦略です.
- この方法は,新しい触媒材料を発見するための他の単原子触媒 (ISAS-M/HNCS) を合成するために拡張できます.
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