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Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
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非対称な触媒のための水素結合ドナーによるルイス酸強化

Steven M Banik1, Anna Levina1, Alan M Hyde1

  • 1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA.

Science (New York, N.Y.)
|November 11, 2017
PubMed
まとめ

チラル・スクワラミドは,シリル・トリフラートでルイス酸複合体を形成することによって,非反応性電ophilesを活性化します. これは,新しい水素結合触媒による有価な化合物のエナチオ選択的合成を可能にします.

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