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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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安定したプッシュプルジセレン: SiSiダブルボンドによる実質的なドナー-受容体相互作用

Tomoyuki Kosai1, Takeaki Iwamoto1

  • 1Department of Chemistry, Graduate School of Science, Tohoku University , Aoba-ku, Sendai 980-8578, Japan.

Journal of the American Chemical Society
|December 2, 2017
PubMed
まとめ

研究者は最初のプッシュプルジレンを合成し 重要な電子相互作用を示しました この新しい化合物は,赤色シフトの吸収帯を示し,処理時にH2割れを受けます.

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Characteristics of the diene
Conformation
The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable,...
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Generally, the best dienophiles are alkenes containing electron-withdrawing substituents such as carbonyl, nitrile, and nitro groups. The feasibility of a Diels–Alder reaction depends...
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The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.
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