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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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機能的に密度の高い四次炭素へのドミノプロセスは,Pd-カタライズされたデカルボキシラティブC ((sp3) -C ((sp3) 結合形成を経由する

Wusheng Guo1, Rositha Kuniyil1, José Enrique Gómez1

  • 1Institute of Chemical Research of Catalonia (ICIQ) , Barcelona Institute of Science and Technology , Av. Països Catalans 16 , 43007 Tarragona , Spain.

Journal of the American Chemical Society
|January 17, 2018
PubMed
まとめ

研究者は,ビニルサイクル炭酸塩を変換することで,複雑な四次炭素を生成する新しいPd触媒方法を開発しました. この効率的な室温プロセスは,新しいCsp3-Csp3結合とステレオ制御の有価なアリル基を形成します.

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