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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

20.3K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.3K
Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

55.8K
Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
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Metallic Solids02:37

Metallic Solids

21.0K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.0K
ABC Transporters: Exporter01:31

ABC Transporters: Exporter

6.7K
ATP-binding cassette or ABC transporter is the largest superfamily of integral membrane proteins. The transporters have transmembrane-binding domains (TMDs) and nucleotide-binding domains (NBDs). The TMDs are specific to their substrates, whereas the NBDs are similar to engines that complete ATP hydrolysis to complete the substrate transport. They can be full transporters consisting of two TMDs and NBDs, half transporters with one TMD and NBD, while some encoded with a single TMD or NBD are...
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ABC Transporters: Importer01:27

ABC Transporters: Importer

3.6K
ATP-binding cassette or ABC transporters are a class of ATP-driven pumps that hydrolyze ATP to move solutes across the membrane. They can be grouped into importers and exporters. While exporters are present in all domains of life, importers exist only in bacteria and some plants.
In bacteria, based on the number of transmembrane helices and the chemical nature of their substrates, the ABC importers can be divided into three types:
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Structures of Solids02:22

Structures of Solids

18.9K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
18.9K

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Updated: Feb 15, 2026

Author Spotlight: Integrating 2D-HPLC-MS and Molecular Networking in Natural Medicine Analysis
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Author Spotlight: Integrating 2D-HPLC-MS and Molecular Networking in Natural Medicine Analysis

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6組分分子固体:ABC[D1-(x+y)ExFy]2

Mithun Paul1, Shaunak Chakraborty1, Gautam R Desiraju1

  • 1Solid State and Structural Chemistry Unit, Indian Institute of Science , Bangalore 560012, India.

Journal of the American Chemical Society
|January 23, 2018
PubMed
まとめ

研究者は6つの構成要素からなる 複雑な分子固体を 作り出すための新しい戦略を開発しました この方法は,連続したコクリスタル形成と固体溶液の組み込みを使用して,複雑な超分子構造を構築します.

科学分野:

  • クリスタル・エンジニアリング
  • 超分子化学
  • 材料科学

背景:

  • マルチコンポーネント分子固体の設計は,結晶パッキングとステキオメトリーの制御において重要な課題を提示します.
  • 以前の戦略は,結晶学的な不等価性が欠如しているため,高次元の共結晶形成を達成する際にしばしば制限に直面します.
  • 低次元のコクリスタルを高次元の構造のステップストーンとして使用する概念が探求されています.

研究 の 目的:

  • 6つの分子固体の合成のための堅固な戦略を開発する.
  • 合成の限界を克服する 四次性コクリスタル.
  • 既存の水晶格子に新しいコンポーネントを組み込むことを探求する.

主な方法:

  • ステキオメトリック四次共結晶形成に関するプロトコルの開発
  • 連続したコンポーネントの置換のための結晶学的不等価性の利用.
  • ハロゲン化およびメチル化リゾルシノール (例えば,CRES,BRES,MRES) の形状と大きさの類似性を利用して,合成のデッドエンドを回避する.
  • 固体溶液形成による追加成分の組み込み

主要な成果:

  • 合成経路が確立され バイナリから高級コクリスタルへと進んだ

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Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
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Site-Directed Immobilization of Bone Morphogenetic Protein 2 to Solid Surfaces by Click Chemistry
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Last Updated: Feb 15, 2026

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  • 四次共結晶レベルでの合成の行き詰まりが特定され,克服されました.
  • 5組分と6組分の分子固体が数多く合成されました.
  • 第五の成分と第六の成分は,第四の成分の場所に固体溶液として組み込まれました.
  • 結論:

    • 開発された戦略は,複雑な多成分分子固体の合理的な設計と合成を可能にします.
    • 複雑な超分子構造の構築には 結晶学的な環境と 構成要素の類似性を利用することが重要です
    • このアプローチは,精密な分子組立を通して,調整可能な性質を持つ新しい材料への実行可能な経路を提供します.