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アルデヒドをアルコールで直接エナチオ選択的α-ベンジル化

Eric D Nacsa1, David W C MacMillan1

  • 1Merck Center for Catalysis , Princeton University , Washington Road , Princeton , New Jersey 08544 , United States.

Journal of the American Chemical Society
|February 6, 2018
PubMed
まとめ

この研究は,アルキル化剤としてアルコールを用いてアルデヒドをエナンチオセレクティブアルファベンジル化するための新しい方法を導入しています. スピンセンターシフト (SCS) メカニズムを利用し,効率的な化学合成のためにフォトレドックスとオーガノカタリシスを組み合わせます.

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