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Updated: Feb 14, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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マルチメタリック Ni-とPd-カタライズされたクロスエレクトロフィールカップリングにより,高度に置換された1,3-ダイエンが形成される

Astrid M Olivares1, Daniel J Weix1,2

  • 1University of Rochester , Rochester, New York 14627-0216, United States.

Journal of the American Chemical Society
|February 9, 2018
PubMed
まとめ

この研究は,ビニルブロミドとビニルトリフラートの結合を用いて,高度に置換された1,3-ダイエンを合成するための新しい方法を導入している. この新しい反応は,ニッケルとパラジウム複合体によって触媒され,以前はアクセスが困難だった複雑なダイエンを効率的に生成します.

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