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Updated: May 5, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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4'-ピリミジニル-機能化された4,2':6',4''-テルピリジン:溶液からの金属有機組立物とAu{11}とCu{11}の表面プラットフォーム

Thomas Nijs1, Y Maximilian Klein2, S Fatemeh Mousavi1

  • 1Department of Physics, University of Basel , Klingelbergstrasse 82, 4056 Basel, Switzerland.

Journal of the American Chemical Society
|February 10, 2018
PubMed
まとめ

この研究では,溶液と表面での銅-テルピリジン複合体の結晶の成長を比較しています. 表面上では,これらの金属有機フレームワークは,温度と基板によって影響される多孔ネットワークや梯子モチーフを含む多様な構造を形成します.

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Stereoisomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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