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スピンペアリングを誘導するα-ヒドリド移動による塩基のない鉄水素烯複合体

Patrick W Smith1, T Don Tilley1

  • 1Department of Chemistry , University of California, Berkeley , Berkeley , California 94720-1460 , United States.

Journal of the American Chemical Society
|March 13, 2018
PubMed
まとめ

新しい鉄ヒドロシリレン複合体が合成され,ユニークな反応性を示した. これらの複合体はC-H活性化され,水素と素早く反応し,結合活性化反応においてルテニウム類を上回る.

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