[Re (L) (CO) (n+) ]複合体における補助リガンドを用いたILCT寿命の劇的な変化:統合されたスペクトロスコピックおよび理論的研究

Georgina E Shillito1, Thomas B J Hall1, Dan Preston1

  • 1Department of Chemistry , University of Otago , P.O. Box 56 , Dunedin , New Zealand.

まとめ

補助リガンドは,レニウム複合体における興奮状態の寿命を大きく変化させ,2つの量位で変化する. この変動は,非放射性崩壊率と放射能を相関させるエネルギーギャップ法によって説明される.

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