還元性O2結合により,二酸化化合物により,レドックス相互変換可能なμ-1,2-ペロキソとμ-1,2-スーペロキソディニッケル (II) の中間物質が生じる

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Updated: Feb 12, 2026

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Published on: March 25, 2017

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Peng-Cheng Duan, Dennis-Helmut Manz, Sebastian Dechert

    Journal of the American Chemical Society
    |March 30, 2018
    PubMed
    まとめ

    この研究は,最初に特徴づけられたμ-1,2-ペロキソジニケルの中間物質を含む,新しいニッケル-酸素複合体を報告している. これらの安定した種は逆転的に相互変換され,ダイオキシゲン活性化と触媒化の新しい経路を提供します.

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