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Ni-Co-A (A = P,Se,O) ナノシートの二重調節 アニオン置換と効率的な水素進化のためのホリー工学
Zhiwei Fang1, Lele Peng1, Yumin Qian1
1Materials Science and Engineering Program and Department of Mechanical Engineering , The University of Texas at Austin , Austin , Texas 78712 , United States.
Journal of the American Chemical Society
|April 3, 2018
まとめ
研究者らは,効率的な水素進化反応 (HER) のための地球に豊富な混合移行金属 (MTM) 電触媒を開発した. Ni-Co-A材料におけるの置換は,水分裂のためのHERの活性と耐久性を著しく高めました.
科学分野:
- 材料科学
- 電気化学
- キャタリシス
背景:
- 効率的なエネルギー変換には 地球に豊富な電気触媒が不可欠です
- 混合移行金属 (MTM) 材料は,水素進化反応 (HER) 触媒に希望を示しています.
- MTM電触媒の特性に対するアニオン効果を理解することは不可欠です.
研究 の 目的:
- HERに対するMTMベースの触媒の電気触媒特性に対するアニオン種の影響を調査する.
- HERの効率と耐久性を高める新しいMTM電触媒を開発する.
- アニオン改変MTM触媒における構造-特性関係を解明する.
主な方法:
- モデル電触媒としてのホーリー Ni/Co ベースのフォスフィード/セレニド/酸化物 (Ni-Co-A) の合成
- HER活性と耐久性試験を含む電気化学的特徴付け
- 電気伝導性の測定と密度関数理論 (DFT) の計算.
主要な成果:
- 置換は電子構成を調節し,Ni-Co-Aナノ構造における水素吸収エネルギーを低下させた.
- NCP (Ni-Co-P) ホーリーナノシート触媒は,HERに対する超低発起ポテンシャルと58mVのポテンシャルを示した.
- 触媒は長時間耐久性を示し,1.56Vで全体的な水分裂を容易にした.
結論:
- アニオン種は,HERのMTMベースの触媒の固有の電気触媒特性に大きな影響を及ぼします.
- を代用したNi-Co-A材料は,水分解のための高効率で耐久性の高い非貴金属電触媒です.
- この研究は,再生可能エネルギーアプリケーションのための高度な電気触媒の設計のための洞察を提供します.
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