3Dアニオンシリケート共性有機フレームワーク srs トポロジー
Oussama Yahiaoui1, Andrew N Fitch2, Frank Hoffmann3
1Department of Chemistry , Technische Universität Berlin , BA2, Hardenbergstraße 40 , 10623 Berlin , Germany.
Journal of the American Chemical Society
|April 5, 2018
まとめ
研究者は,ハイパーコーディネートシリコンノードを使用して新しいアニオン3D共性有機フレームワーク (COF) を合成しました. SiCOF-5という新しい材料は 独特のサーズネットトポロジーを採用し,高度な多孔性材料の可能性を広げています
科学分野:
- 材料化学
- 超分子化学
- ナノテクノロジー
背景:
- 新しいトポロジーで3D共性有機フレームワーク (COF) を合成することは困難です.
- 既存の3D COFは,四面体構造ブロックに限定されています.
研究 の 目的:
- アニオンの3DCOFを3つの座標網で標的として合成することを実証する.
- COF構造の幾何学的多様性を拡大する.
主な方法:
- ハイパーコーディネートシリコンノードに基づくアニオンシリケートCOFの新しい結合を用いた.
- 網状のダイアニオン六合座標 [SiO6]2-ノードでトリフェニレンを構成している.
- 制御された核化と成長率 段階的なシリコン源生成
主要な成果:
- SiCOF-5というアニオンの3DCOFを 合成した.
- SiCOF-5は,二重の相互浸透したsrs-c網で結晶する.
- フレームの組成はNa2[Si(C18H6O6) ]である.
結論:
- srs net トポロジを持つ新しいアニオン3D COFの標的合成を達成しました.
- COFの構築におけるハイパーコーディネートシリコンノードの有用性を実証した.
- 結晶化に成功するために制御された反応運動の重要性を強調した.
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