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Updated: Feb 12, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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クロロアルキンと非活性化アルケンの間のオカタライズされた分子間 [2+2] サイクル添加

Yu-Bin Bai1,2, Zaigang Luo2, Yuguang Wang2

  • 1Shaanxi Key Laboratory of Natural Products & Chemical Biology, College of Chemistry & Pharmacy , Northwest A&F University , Yangling 712100 , China.

Journal of the American Chemical Society
|April 6, 2018
PubMed
まとめ

ゴールド触媒は,クロロアルキンの非活性化アルケンとの効率的な [2+2] サイクル添加を可能にし,単体置換されたアルケンにさえ挑戦します. この金触媒反応は,価値あるサイクロブテンの産物を合成するための優れた地域選択性とステレオ特異性を提供します.

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