リサイクル可能で,強度があり,高度に形性のある,ボロキシンネットワークに基づく熱セット

William A Ogden¹, Zhibin Guan¹

¹Department of Chemistry , University of California , Irvine , California 92697 , United States.

Journal of the American Chemical Society

|May 8, 2018

まとめ

研究者らはボロキシンダイナミック・クロスリンクを用いて再利用可能な新型耐熱材料を開発した. 水で加熱すると元々のモノマーに再構成され持続可能な代替材料となるのです

科学分野:

材料科学
ポリマー化学
超分子化学

背景:

伝統的な耐熱材料は優れた性能を備えているが再処理やリサイクルには欠けている.
小分子ボロキシンは可逆的な交換反応を示し,ダイナミックな材料設計の機会を提供します.

研究の目的:

機械的性質と再利用性を向上させる新しい熱固体材料を設計する
熱固体ネットワークのダイナミッククロスリンクにボロキシンの可逆化学を活用する.

主な方法:

ボロキシンベースの熱固体ネットワークの合成
ダイナミックな機械的性質の特徴
水中の熱処理による再利用性の調査.

主要な成果:

ボロキシン・ダイナミック・クロスリンクを使って強くて柔軟な熱固体材料を合成しました
材料は水で加熱するとモノメア成分に戻すことができることが実証された.
新しいボロキシンネットワークのダイナミックな機械的振る舞いを特徴づけた.

結論:

ボロキシンベースのダイナミック・クロスリンクは,強固で柔軟で再利用可能な熱固体材料を作るのに有効な経路を提供します.
開発されたシステムは,調整可能な特性を有する新しいダイナミックな材料を設計するための汎用的なプラットフォームを提供します.
このアプローチは,再処理とリサイクルに関する従来の熱固体の限界に対処します.

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