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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Inductance: Solid Cylindrical Conductor01:24

Inductance: Solid Cylindrical Conductor

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To calculate the inductance of a solid cylindrical conductor, consider a 1-meter section of a non-magnetic, current-carrying conductor with radius r. Disregarding end effects and assuming uniform current density, Ampere's law helps determine the magnetic field inside the conductor. This law states that the magnetic field intensity H is concentric and constant within the conductor.
Given the uniform current distribution, the magnetic field Hx and flux density Bx inside the conductor are...
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Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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固体電池のインターフェースダイナミクスを強化するために,イオン導体層を通じたカソド-固体電解質のインターフェースポテンシャルドロップを緩和する.

Jia-Yan Liang1,2, Xian-Xiang Zeng3, Xu-Dong Zhang1,2

  • 1CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry , Chinese Academy of Sciences (CAS) , Beijing 100190 , P. R. China.

Journal of the American Chemical Society
|May 19, 2018
PubMed
まとめ
この要約は機械生成です。

新しいトランジション層は 固体電池の性能を向上させ インターフェイスの極化を減少させます これは,次の世代の高性能固体電池のサイクル安定性と速度能力を高めます.

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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科学分野:

  • 材料科学
  • 電気化学
  • 固体電池

背景:

  • 固体電池は,キャソードと電解質の接触が悪いこととインターフェイスの極化により,容量低下の課題に直面しています.
  • これらのインターフェースの問題を緩和することは,固体電池で高い電力密度を達成するために不可欠です.

研究 の 目的:

  • 固体電池の性能を向上させるためのLi+伝導性移行層を導入し,調査する.
  • バッテリーのダイナミクスと安定性を向上させるインターフェースメカニズムを理解する.

主な方法:

  • Li1.4Al0.4Ti1.6をLiNi0.6Co0.2Mn0.2O2のカトドに塗布する.
  • 境界ポテンシャル分析による原子力顕微鏡を用いて,界面特性を調査する.

主要な成果:

  • 移行層はインターフェイスの偏分を効果的に緩和し,漸進的な潜在的な傾きを提供します.
  • 改造されたカトッドは,室温で改善されたサイクル安定性 (100サイクル後に90%) と優れた速度能力 (116 mAh g-1) を示した.

結論:

  • 開発されたインターフェイス移行層は,固体電池の電気化学性能を大幅に向上させます.
  • この研究は,将来の固体電池技術の進歩のためのインターフェースエンジニアリングの洞察を提供します.