カルコゲン結合相互作用によって誘発される超分子膀とナノファイバーの可逆的自己組み立て
Liang Chen1, Jun Xiang2, Yue Zhao2
1Key Laboratory of Molecular Engineering of Polymers , Fudan University , Shanghai 200433 , China.
Journal of the American Chemical Society
|May 30, 2018
まとめ
研究 者 たち は,カルコゲン 結合 (Te·O または Se·O) を 活用 し て,新しい 超アンフィフィール を 作り まし た. これらの分子は自己組織化して 超分子やナノファイバーとなり 超分子化学の新たな可能性が生まれます
科学分野:
- 超分子化学
- 材料科学
- 化学物理学
背景:
- カルコゲン結合は,新たな非共性相互作用である.
- 分子自己組み立てのためのカルコゲン結合の利用は,ほとんど未探究のままである.
研究 の 目的:
- カルコゲン結合による 超アンフィフィルの最初の事例を報告する
- これらの新種の分子が ナノ構造に組み合わされる過程を 調べるためでした
主な方法:
- 準カリックス[4]カルコゲナジアゾール (C4Ch) マクロサイクルドナーの設計.
- 尾状のピリジンN酸化表面活性剤を分子受容体として設計.
- Te·OまたはSe·Oカルコゲン結合によるドナー-受容体複合体の形成
主要な成果:
- カルコゲン結合の相互作用によって新しい超アンフィフィルの形成に成功した.
- 超分子ベシクルとナノファイバーの自己組み立ての実証
- ナノ構造の幾何学的な制御は,カルコゲン結合の親和によって決定される.
結論:
- カルコゲン結合は,スーパーアンフィフィルの形成を効果的に誘導する.
- カルコーゲン結合の相互作用を調節することで,様々な自己組み立てナノ構造が達成できます.
- ナノ構造の可逆分解は 競合するイオンやpHの変化によって可能である.
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