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Updated: Feb 8, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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グループ4のダイアルキル複合体のM-C結合にイソニトリルの挿入

Jiawei Chen1, Nadine Yassin2, Thilina Gunasekara1

  • 1Department of Chemistry , Columbia University , 3000 Broadway , New York , New York 10027 , United States.

Journal of the American Chemical Society
|June 17, 2018
PubMed
まとめ

束縛された幾何学リガンドを持つグループ4の金属複合体は,ダイエンとイソニトリルと反応する. タイタンはチタン-アジリジンを形成し,ジルコニウムとハフニウムは複雑なダイアザメタラサイクロペンタン誘導体を生成し,異なる反応経路を明らかにする.

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