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N2結合モードの鉄基機能化による二酸化窒素の鉄 (III) 水素複合体の形成への影響

Sean F McWilliams1, Eckhard Bill2, Gudrun Lukat-Rodgers3

  • 1Department of Chemistry , Yale University , 225 Prospect Street , New Haven , Connecticut 06520 , United States.

Journal of the American Chemical Society
|June 30, 2018
PubMed
まとめ

鉄-二酸化窒素複合体を比較すると,単体鉄 ((0)) 二酸化窒素化合物は二核複合体よりもシル化反応性が高いことが明らかになる. この反応性は,生成された鉄 (III) 水素複合体に影響する.

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