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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

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アリルボラネット活性化アルキルグリナード反応剤を用いたエナンチオセレクティブ銅触媒除

Minyan Wang1, Xinghui Pu1, Yunfei Zhao1

  • 1State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering , Nanjing University , Nanjing 210093 , China.

Journal of the American Chemical Society
|July 11, 2018
PubMed
まとめ

この研究は,アルケンのエナチオセレクティブ・デフローロアルキル化のための新しい銅触媒法を導入し,貴重なジェム・ディフローロアルケンを生み出します. アリルボラネートで活性化されたグリナード反応剤は,このC-F活性化クロスカップリング反応の鍵でした.

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