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Updated: Feb 8, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

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金属触媒によるC-HとC-O機能化を統合して,アレーンアシレーションでステリック制御された地域選択性を達成する

Nicholas A Serratore1, Constance B Anderson1, Grant B Frost1

  • 1Department of Chemistry , University of Minnesota-Twin Cities , 207 Pleasant Street SE , Minneapolis , Minnesota 55455 , United States.

Journal of the American Chemical Society
|July 11, 2018
PubMed
まとめ

この研究は,リジオセレクティブアレンアシレーションのための新しいイリジウム触媒反応をサリシラートエステルを用いて導入している. この方法は,ステリック制御されたC-C結合形成を達成し,価値あるベンゾフェノン誘導体を合成するために従来の電気的芳香的置換の代替案を提供します.

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