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Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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電子移転反応:可視光による活性化により,KO tBu (NaO tBuではない) がベンゾフェノンを還元する

Giuseppe Nocera1, Allan Young1, Fabrizio Palumbo1

  • 1Department of Pure and Applied Chemistry , University of Strathclyde , 295 Cathedral Street , Glasgow , G1 1XL , U.K.

Journal of the American Chemical Society
|July 12, 2018
PubMed
まとめ

カリウム三酸化物からベンゾフェノンへの電子移転は,直接ではなく,光活性化されます. カリウム結合複合体は,光にさらされたときに電子の移転を可能にし,アルカリ金属の選択性が観察されています.

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