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陽子結合レドックススイッチングは,無効化されたπ拡張コア変形オクタフィリン

Tridib Sarma1,2, Gakhyun Kim3, Sajal Sen2

  • 1Center for Supramolecular Chemistry & Catalysis , Shanghai University , Shanghai 200444 , China.

Journal of the American Chemical Society
|September 6, 2018
PubMed
まとめ

新しいオクタフィリンは,レドックスベースのスイッチングのために,陽子結合電子移転 (PCET) を受けます. この発見により,プロトネーションによる2電子の還元が容易になり,新しい合成システムが可能になった.

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