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Updated: Feb 5, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

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黄金の表面上のN-ヘテロサイクルカルベンの結合方式を解明する

Anne Bakker1,2, Alexander Timmer1,2, Elena Kolodzeiski1,2,3

  • 1Physikalisches Institut , Westfälische Wilhelms-Universität , Wilhelm-Klemm-Straße 10 , 48149 Münster , Germany.

Journal of the American Chemical Society
|September 12, 2018
PubMed
まとめ

アルキル鎖の長さは,N-ヘテロサイクルカルベン (NHCs) が金表面に結合する方法を制御する. 短い鎖は直立結合を好み,長い鎖は平らなNHC-Au-NHC複合体を導いて,マテリアルデザインを可能にします.

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