シルバー メタル を ミスレン に 塗り替える
Brittany Trang1, Matthew Yeung1, Derek C Popple1,2
1The Molecular Foundry , Lawrence Berkeley National Laboratory , One Cyclotron Road , Berkeley , California 94720 , United States.
Journal of the American Chemical Society
|September 29, 2018
まとめ
銀とディフェニルディセレニドを用いた 発光性半導体薄膜を作る 新しい方法が開発されました この簡単なプロセスは,先進的な光電子材料への新しい経路を提供します.
科学分野:
- 材料科学
- ナノテクノロジー
- 固体化学
背景:
- 銀の汚れは酸化と塩の降水を含みます.
- 薄い金属硫化物膜を作る方法である.
- このプロセスは,光電子特性を持つ高度な材料に適応することができます.
研究 の 目的:
- ミトレン (銀ベンゼンセレノラート) の発光半導体薄膜を準備する.
- ディフェニルディセレニドを硫黄の代替源としてフィルム製造に使用する.
- これらの新鮮な薄膜の光電子特性を探求する.
主な方法:
- ディフェニルディセレニドを用いた金属銀薄膜の腐食.
- 結晶固体としてのミトレン (銀ベンゼンセレノ酸) [AgSePh]∞の形成
- 大面積の薄膜 (5-100 nm 厚さ) の光学特性の特徴.
主要な成果:
- 発光性半導体ミトレン薄膜を成功裏に製造した.
- ミトレンは有機上分子と2D無機協調ポリマー相の両方を表しています.
- 化合物の光学特性は,ウエファースケールフィルムを使用して測定された.
結論:
- この方法は,有機-無機カルコゲノレート薄膜のハイブリッドへの簡単な経路を提供します.
- 温和な温度でウエファースケール加工は可能である.
- 半導体デバイスと階層的なアーキテクチャにおける潜在的な応用
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