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Updated: Feb 4, 2026

Laboratory-determined Phosphorus Flux from Lake Sediments as a Measure of Internal Phosphorus Loading
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Laboratory-determined Phosphorus Flux from Lake Sediments as a Measure of Internal Phosphorus Loading

Published on: March 6, 2014

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P,P-ディメチルフォーマルフォスフィン:N,N-ディメチルフォーマミッドのリン類

Kevin M Szkop1, Andrew R Jupp1, Douglas W Stephan1

  • 1Department of Chemistry , University of Toronto , 80 St. George Street , Toronto , Ontario M5S3H6 , Canada.

Journal of the American Chemical Society
|October 2, 2018
PubMed
まとめ

研究者らは,ゲルマニウムを含む前体から,ホルマミドの類化合物を合成した. これらのフォスフィンはルテニウムとのユニークな協調化学を示し,PとNを含む分子比較の洞察を提供します.

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Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
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To understand this phenomenon, consider the elementary reaction:
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