水・ガスシフト反応のためのカルバイドサポートAu触媒:強力な金属サポート相互作用効果のための新しい領域
Jinhu Dong1,2, Qiang Fu1, Zheng Jiang3
1State Key Laboratory of Catalysis, iChEM , Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023 , China.
Journal of the American Chemical Society
|October 4, 2018
まとめ
モリブデン炭化物上の金のナノ粒子は,低温水ガスシフト反応 (LT-WGSR) の活性を増強する強力な金属支柱相互作用 (SMSI) を表しています. このSMSI状態は,金属/炭化水素の触媒に逆転し,新しい触媒の可能性を開きます.
科学分野:
- 異質な触媒
- 材料科学
- 表面化学
背景:
- 強い金属支柱相互作用 (SMSI) は,通常,金属/酸化物系で研究される異質触媒において極めて重要です.
- 金属/炭化水素の触媒におけるSMSIの役割は,まだほとんど研究されていない.
- SMSIを理解することは,高度な触媒材料を設計する上で鍵となるものです.
研究 の 目的:
- 金/モリブデン炭化物 (Au/MoC_x) 触媒におけるSMSIの存在と影響を調査する.
- Au/MoC_x システムにおけるインターフェースの電子状態と触媒活動の関係を調べる.
- 金属/炭化水素触媒におけるSMSIの調節性を実証する.
主な方法:
- Au/MoC_x触媒の合成について
- 触媒の構造,分散,および電子特性の特徴
- 低温水ガスシフト反応 (LT-WGSR) の触媒活性評価
- 炭化と酸化した触媒状態の比較研究.
主要な成果:
- 炭化Au/MoC_x触媒は,高度に分散したゴールドオーバーレイヤーと,活発なSMSI状態を示す強力なインターフェイスチャージ転送を示した.
- これらのアクティブSMSI触媒は優れたLT-WGSR性能を示した.
- 酸化処理により金ナノ粒子の集積,電子相互作用の弱まり,LT-WGSRの活性が低下した.
- 触媒のインターフェース状態は,炭素化と酸化サイクルを通じて,活性SMSIと非活性状態の間で可逆的に切り替えられた.
結論:
- この研究では,炭化によって誘発された金/モリブデン炭化ガスの触媒にSMSI効果が活性化されていることが示されています.
- これらの発見は,SMSI現象における金属/炭化物インターフェースの可能性を強調しています.
- SMSI状態の可逆性は,触媒プロセスを設計し制御するための新しい道を提供します.
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