エチレンに対するアセチレン選択的吸収のための結晶型ポリイミドの多孔な有機フレーム
Lingchang Jiang1, Yuyang Tian2, Tu Sun3
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry , Jilin University , Changchun 130012 , China.
Journal of the American Chemical Society
|October 27, 2018
まとめ
新しい多孔性材料であるPAF-110は,エチレンよりもアセチレンを選択的に吸収し,純粋なエチレン生産の重要なステップです. この安定した材料は,石油化学産業のための強化された分離能力を提供します.
科学分野:
- 材料科学
- 化学工学
- 分離科学
背景:
- アセチレン不純物はエチレンポリメリゼーションを阻害し,効率的な分離方法を必要とします.
- 現在の分離技術は,高い純度と効率を達成する上で課題に直面しています.
研究 の 目的:
- 選択的なアセチレン吸収のための新しい多孔な有機物質を合成し,特徴づけること.
- アセチレンからエチレンを分離する材料の安定性と性能を調査する.
主な方法:
- ナフタレン・ダイアンヒドリドとトリス ((4-アミノフェニル) アミンのイミジ化によるPAF-110の合成.
- 熱重量測定分析と粉末X線微分を用いた特徴付け.
- 異なる温度と圧力でのガス吸着の研究
主要な成果:
- PAF-110は高い熱と構造の安定性を示した.
- 材料は273Kのエチレンよりも2倍以上のアセチレン吸収能力を示した.
- 適度なアセチレン選択性 (3. 9) は,静電相互作用に起因する298Kで観察された.
結論:
- PAF-110は,エチレンよりも選択的なアセチレン吸収を示す最初の結晶性多孔な有機物質です.
- この発見は,石油化学産業における重要なガス分離のための高度な多孔性の材料の設計のための洞察を提供します.
関連する概念動画
Polymer Classification: Crystallinity
4.0K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
4.0K
Analyte Adsorption and Distribution
2.8K
In certain chromatographic separations, solutes transfer between the mobile phase and the stationary phase via sorption, which typically refers to the process of adsorption. For many chromatographic systems, the sorption process often depends on the polarity of the compounds—an expression of the overall dipole moment within the molecule. During the separation process, there is competition between the solute and solvent for adsorption to the stationary phase. Highly polar compounds and...
2.8K
What is Natural Selection?
129.2K
Natural selection is an evolutionary process in which individuals with survival-promoting traits reproduce at higher rates. These favorable traits become more common within a population or species. Naturally selected traits initially arise via random genetic mutations. In order for selection to occur, there must be variation within a population, the trait controlling the variation must be heritable, and there must be an evolutionary advantage for variation in the trait.
129.2K
Antibiotic Selection
59.9K
Overview
59.9K
Levels of Organization
140.8K
Biological organization is the classification of biological structures, ranging from atoms at the bottom of the hierarchy to the Earth's biosphere. Each level of the hierarchy represents an increase in complexity that builds upon the previous level.
Molecules Are Composed of Atoms, and Biomolecules Are Assembled from Molecules:
The most basic levels include atoms, molecules, and biomolecules. Atoms, the smallest unit of ordinary matter, are composed of a nucleus and electrons. Molecules...
Molecules Are Composed of Atoms, and Biomolecules Are Assembled from Molecules:
The most basic levels include atoms, molecules, and biomolecules. Atoms, the smallest unit of ordinary matter, are composed of a nucleus and electrons. Molecules...
140.8K
Accessory Organs
74.2K
Accessory organs are those that participate in the digestion of food but do not come into direct contact with it like the mouth, stomach, or intestine do. Accessory organs secrete enzymes into the digestive tract to facilitate the breakdown of food.
74.2K


