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Updated: Feb 3, 2026

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

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SmI2-水による陽子結合電子移転によるカルボニルの減少における基板と陽子ドナー調整の相互作用

Tesia V Chciuk1, William R Anderson1, Robert A Flowers1

  • 1Department of Chemistry , Lehigh University , 6 E. Packer Avenue , Bethlehem , Pennsylvania 18015 , United States.

Journal of the American Chemical Society
|November 1, 2018
PubMed
まとめ

サマリウム二酸化物 (SmI2) の水によるカルボニル還元は,段階的な電子移転-陽子移転ではなく,陽子結合電子移転 (PCET) を経由する. ステリック阻害と基質の調整は反応速度に大きな影響を及ぼし,PCETが支配的なメカニズムであることを確認した.

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