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Updated: Feb 3, 2026

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BF3- プロモートされた,カルベンのような,ベンジンのC-H挿入反応

Hang Shen1, Xiao Xiao1, Moriana K Haj1

  • 1Department of Chemistry , University of Minnesota , 207 Pleasant Street , SE Minneapolis , Minnesota 55455 , United States.

Journal of the American Chemical Society
|November 3, 2018
PubMed
まとめ

ボロン三化物 (BF3) は,緊張したpi結合を活性化することでベンジンC-H挿入反応を活性化します. このルイス酸はカーベンのような性質を与え,過渡性金属に前例のない触媒活性をもたらします.

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