無鉛ハリド二重ペロフスキットから発生する,効率的で安定した暖かい白色の光
Jiajun Luo1, Xiaoming Wang2, Shunran Li1
1Sargent Joint Research Center, Wuhan National Laboratory for Optoelectronics (WNLO) and School of Optical and Electronic Information, Huazhong University of Science and Technology (HUST), Wuhan, China.
Nature
|November 9, 2018
まとめ
研究者は新しい無鉛のダブルペロブスキットを開発し 効率的な白光放射を可能にしました この材料はCs2 ((Ag0.60Na0.40) InCl6で 安定した高効率の照明を提供し 先進的な照明技術への道を切り開いています
科学分野:
- 材料科学
- 固体物理学
- 光学について
背景:
- 照明は世界の電気の20%を消費し 効率的な光源の需要を高めています
- シングルマテリアルのホワイトライトエミッターは,全可視スペクトルエミッションを達成することが困難である.
- 現存する金属ハリドペロブスキットは良い排出量ですが,鉛を含み,安定性が欠けている.
研究 の 目的:
- 効率的で安定した白光発射のための無鉛のペロブスキート材料を開発する.
- 二重ペロブスキットの効率的な光放出のメカニズムを調査する.
- 照明アプリケーションの光発光効率と安定性を高める.
主な方法:
- ナトリウムをCs2AgInCl6に合金して合成された無鉛の二重ペロブスキート.
- 光の放出に関する自己捕捉エクシトンとヤーン・テラー歪曲を調査した.
- 光発光性を高めるための最適化組成とドーピング (ビスムート)
主要な成果:
- 無鉛のダブルペロブスキットから効率的な白光放射が達成された,Cs2 ((Ag0.60Na0.40) InCl6.
- 純粋なCs2AgInCl6と比較して,光発光効率の3度増加を示した.
- 最適化された材料は86%の量子効率と 1,000時間以上の安定した動作を示した.
結論:
- 安定した無鉛のダブルペロブスキットを開発し,効率的な白光放射を可能にしました.
- 材料の性能は自己捕捉されたエキストンと 電子的次元性の減少によるものです
- この研究は,次世代の照明とディスプレイのための単一発光灯とダイオードの研究を促進します.
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