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Updated: Feb 2, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

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毛穴のある結晶における好ましい光反応,金属マクロサイクルフレームワーク:PdII-メディエートされたオレフィン移動 [2+2]サイクル添加

Hirotaka Yonezawa1, Shohei Tashiro1, Takafumi Shiraogawa2

  • 1Department of Chemistry, Graduate School of Science , The University of Tokyo , 7-3-1 Hongo , Bunkyo-ku, Tokyo 113-0033 , Japan.

Journal of the American Chemical Society
|November 9, 2018
PubMed
まとめ

メタルマクロサイクルフレームワーク (MMF) では,1,6-ダイネは典型的な [2+2] サイクル添加ではなく,光誘導によるオレフィン移動を経験する. この狭い空間は反応性を制御し 望ましくない反応を抑制し 選択的変換を可能にします

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