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ペンタフローロフェニルニトロンのスピン状態の切り替え: シングレットアリルニトロンの複合体の分離

Joel Mieres-Perez1, Paolo Costa1, Enrique Mendez-Vega1

  • 1Lehrstuhl für Organische Chemie II , Ruhr Universität Bochum , 44780 Bochum , Germany.

Journal of the American Chemical Society
|November 16, 2018
PubMed
まとめ

研究者はルイス酸を用いて反応性シングレットアリルニートレンを安定させ,新しい合成経路を可能にしました. これは三重基底状態の限界を克服し,有機合成におけるアリルニートレンの応用への扉を開きます.

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Switching behavior in Bipolar Junction Transistors (BJTs) is a fundamental aspect utilized in various electronic circuits, particularly for digital logic applications like switches and amplifiers. In a typical switching circuit, a BJT alternates between cut-off and saturation modes, corresponding to the "off" and "on" states, respectively, thus behaving like an ideal switch.
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The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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