酸化に敏感な場所のデュテレーションによる高活性均質の水酸化触媒としての鉄調整複合体の設計

Zoel Codolà1, Ilaria Gamba1, Ferran Acuña-Parés2

  • 1Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química , Universitat de Girona , Campus Montilivi, E17071 Girona , Catalonia , Spain.

まとめ

鉄触媒は,水酸化のためのオキシ鉄 (IV) 種を生成する. C-H結合をC-D結合に置き換えることで,酸化鉄ではなく,複合体の安定性と効率が著しく向上します.

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