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Updated: Feb 1, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

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リング開きポリメリゼーションにおけるエピメリゼーションを排除するためのシナジェティック・オルガノカタリスは,ステレオレギュラー・イソタクティック・ポリエステルの合成を可能にします

Maosheng Li1,2, Yue Tao1,3, Jiadong Tang1,3

  • 1Key Laboratory of Polymer Ecomaterials , Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , Renmin Street 5625 , Changchun 130022 , People's Republic of China.

Journal of the American Chemical Society
|December 5, 2018
PubMed
まとめ

この研究は,O-カルボキシアン水素 (OCA) のリング開きポリメリゼーションのための新しい二機能有機触媒を導入します. この方法では,モノマー・ラセミゼーションなしで高同位性ポリエステルを得て,機能性ポリマーの持続的な合成を可能にします.

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