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Updated: Feb 1, 2026

Electrochemical Detection of Deuterium Kinetic Isotope Effect on Extracellular Electron Transport in Shewanella oneidensis MR-1
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Electrochemical Detection of Deuterium Kinetic Isotope Effect on Extracellular Electron Transport in Shewanella oneidensis MR-1

Published on: April 16, 2018

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18O 動態同位体効果は,リン酸脱水素酵素触媒化リン酸移転の関連移行状態を明らかにする

Graeme W Howe1,2, Wilfred A van der Donk1,2,3

  • 1Department of Chemistry , University of Illinois at Urbana-Champaign , 600 South Mathews Avenue , Urbana , Illinois 61801 , United States.

Journal of the American Chemical Society
|December 12, 2018
PubMed
まとめ

リン酸脱水酵素 (PTDH) は,他のリン酸加工酵素とは異なり,リン酸移転のための関連メカニズムを使用する. これは,核愛性の重要な参加と,貧しい水素離脱基による緊密な移行状態を伴う.

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