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C-H活性化のための金属アルキル化合物のπ結合特性:どのように,いつ,そしてなぜ?

Christopher P Gordon1, Damien B Culver2, Matthew P Conley2

  • 1Department of Chemistry and Applied Biosciences , ETH Zürich , Vladimir Prelog Weg 1-5 , 8093 , Zürich , Switzerland.

Journal of the American Chemical Society
|December 12, 2018
PubMed
まとめ

移行金属アルキルのC-H結合の活性化は,特定のメカニズムに関係なく,金属-炭素結合のπ特性に関連している. この発見は,σ結合転移,オレフィン挿入,およびオレフィン転移反応の類似性を明らかにする.

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