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機械 的 変形 は 分子 交差点 の トンネリング 経路 を 識別 する

Zuoti Xie, Ioan Bâldea1, Greg Haugstad

  • 1Theoretische Chemie , Universität Heidelberg , INF 229, D-69120 Heidelberg , Germany.

Journal of the American Chemical Society
|December 12, 2018
PubMed
まとめ

分子結合の機械的な伸縮は 異なる電子トンネルの経路を明らかにします 伸縮アルカネチオール (C nT) は導電性の変化を示さないが,オリゴフェニレンチオール (OPT n) は局所的と非局所的軌道を区別して有意な減少を示している.

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