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レドックス活性リガンドによるウラニル機能化:アサイレーションによるOC結合の生成

Ezra J Coughlin1, Yusen Qiao2, Ekaterina Lapsheva2

  • 1H.C. Brown Laboratory, Department of Chemistry , Purdue University , West Lafayette , Indiana 47907 , United States.

Journal of the American Chemical Society
|December 12, 2018
PubMed
まとめ

研究者は,リドックス活性イミノキノンリガンドでウラニル化合物を合成した. リガンドベースの減少が観察されたが,反応がウラニル結合の割れとU (VI) からU (IV) の減少を引き起こすまで,ウランは六価のままであった.

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