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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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酸化性N-ヘテロサイクリックカルベンの有機触媒の中間基は?

Vianney Regnier1, Erik A Romero2, Florian Molton1

  • 1Univ. Grenoble Alpes , CNRS, DCM , 38000 Grenoble , France.

Journal of the American Chemical Society
|December 19, 2018
PubMed
まとめ

N-ヘテロサイクリックカルベン (NHC) 誘導アルデヒドの酸化は,ブレスロウ中介物から単一の電子移転を経由して行われません. 代わりに,酸化変換はエノラートまたはエノールを含み,中性カプトダティブラジカルを生成します.

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