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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Rh ((III) -アルキンによる催化メタ-C-Hアルキニル化

Hua-Jin Xu1, Yan-Shang Kang1, Hang Shi2

  • 1Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering , Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University , Nanjing 210023 , China.

Journal of the American Chemical Society
|December 27, 2018
PubMed
まとめ

この研究では,第1回Rh (III) 触媒化メタ-C-Hアルケニル化が,代替アルキンを用いて行われています. U型ニトリル模板は反応を指揮し,高選択性を持つ有価な三置換オレフィンと複雑なアリルアルコールを生成する.

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