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Hydrogen Bonds00:26

Hydrogen Bonds

133.1K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
133.1K
Hydrogen Bonds01:04

Hydrogen Bonds

14.1K
A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
14.1K
IR Spectrum Peak Broadening: Hydrogen Bonding01:23

IR Spectrum Peak Broadening: Hydrogen Bonding

1.8K
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker bonds vibrate at lower frequencies. The stretching vibration of the strong O–H bond in alcohols and phenols (very dilute solution or gas phase) appears as a sharp peak at 3600–3650 cm−1.
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular...
1.8K
Organic Compounds03:02

Organic Compounds

57.3K
All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...
57.3K
Peptide Bonds02:43

Peptide Bonds

82.9K
A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
82.9K
Valence Bond Theory02:45

Valence Bond Theory

50.1K
Overview of Valence Bond Theory
50.1K

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Synthesis and Characterization of Functionalized Metal-organic Frameworks

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酸反応性水素結合有機フレームワーク

Ichiro Hisaki1, Yuto Suzuki2, Eduardo Gomez3

  • 1Research Institute for Electronic Science , Hokkaido University , Kitaku, Sapporo , Hokkaido 001-0020 , Japan.

Journal of the American Chemical Society
|January 8, 2019
PubMed
まとめ

新しい多孔性水素結合有機フレームワーク (HOF) は,逆戻り可能な酸誘発色変化を示しています. この発見は スマートで刺激に反応する素材の開発に 新たな道を開きます

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Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
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A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
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A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

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関連する実験動画

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科学分野:

  • 材料科学
  • 超分子化学
  • 有機化学

背景:

  • 水素結合有機フレームワーク (HOF) は,調節可能な性質を持つ結晶材料です.
  • 刺激に反応する材料は 先進的なセンサーと適応技術にとって 極めて重要です

研究 の 目的:

  • 新しい酸反応性HOFの構築と特徴付け
  • HOFの光物理的性質と構造的振る舞いを,酸性曝露時に調査する.

主な方法:

  • 構造的決定のための単結晶X線 difraktion.
  • 孔性の評価のためのガス吸収実験.
  • 光化学の研究のためのフェムト秒光譜と光顕微鏡.

主要な成果:

  • 高熱安定性を有する多孔 HOF (CPHATN-1a) が合成された.
  • 超高速な分子内電荷伝達と単位間陽子伝達反応が観察されました.
  • 酸性蒸気への曝露で可逆的な黄色から赤茶色の色変化と放射変調が示された.

結論:

  • この作品は,酸反応性色の変化を示す最初のHOFを提示しています.
  • 開発されたHOFは,化学センサーとスマート・マテリアルでの応用の可能性を示しています.
  • この発見は,刺激反応性HOFの理解に寄与する.