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非対称的移転水素化と二機能鉄 ((II) 水素:実験は計算を満たす

Lorena De Luca1, Alessandro Passera1, Antonio Mezzetti1

  • 1Department of Chemistry and Applied Biosciences , ETH Zurich , Zurich 8093 , Switzerland.

Journal of the American Chemical Society
|January 10, 2019
PubMed
まとめ

キラル鉄水化物複合体 (5) は非対称ケトン水素化を触媒とする. 鉄酸化物前駆体から形成され,独特のマクロサイクリック構造とイソニトリルリガンドにより高いエナンチオセレクティブ性を達成します.

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