分子スイッチで調節する非共振クロスリンク
Eric S Epstein1,2,3, Luca Martinetti4,3, Ravichandran H Kollarigowda1,2,3
1Beckman Institute for Advanced Science and Technology , University of Illinois at Urbana-Champaign , Urbana , Illinois 61801 , United States.
Journal of the American Chemical Society
|January 22, 2019
まとめ
スピロピラン分子スイッチと金属イオンは 逆転可能なポリマーネットワークを作ります 熱はクロスリンクを誘発し 光はネットワークの破壊を誘発し 刺激に反応するポリマーの設計を可能にします
科学分野:
- ポリマー化学
- 材料科学
- 超分子化学
背景:
- スピロピラン化合物は,外部の刺激に反応する分子スイッチとして知られています.
- 刺激に反応するポリマーは,高度なアプリケーションのために調整可能な性質を提供します.
- 金属とリガンドの相互作用は,ダイナミックな物質ネットワークの構築に不可欠です.
研究 の 目的:
- リバーシブルなポリマークロスリンクナーとして移行金属イオンによるスピロピラン分子スイッチの使用を調査する.
- 熱で誘発されたネットワーク形成と光で誘発されたネットワーク破壊を機能化されたポリマーで実証する.
- 金属イオンバレンスの影響とクロスリンク効率の濃度を調査する.
主な方法:
- スピロピランで機能化されたポリマーの合成
- ポリマー溶液を様々な移行金属塩で作る
- 熱と光の刺激を用いたネットワーク形成と破壊の特徴づけ
- 金属イオンの性質と比率に対するクロスリンク依存性の分析.
主要な成果:
- スピロピラン・メタルイオン系を用いて,可逆的な一時的なネットワーク形成と破壊が達成された.
- 熱刺激により,スピロピランのイソメリゼーションによってメロシアニンの形に誘導される.
- 可視光に曝されることで 金属とリガンドの交互結合が解散し ネットワークが破壊されました
- クロスリンクの効率は,金属イオンの有価性とスピロピランと金属塩のモラ比に依存した.
結論:
- スピロピラン・メタルイオン系は,刺激に反応する可逆性ポリマーネットワークの構築に多用途なプラットフォームを提供します.
- このアプローチは,熱,光,そして潜在的にpHや力などの刺激に反応するポリマーを設計するための基盤を提供します.
- この発見は,調整可能な機械的および粘着弾性特性を有する新種のスマート素材への道を開きます.
関連する概念動画
Noncovalent Attractions in Biomolecules
64.9K
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
64.9K
Noncovalent Attractions in Biomolecules
19.5K
19.5K
Crossing Over
171.9K
Unlike mitosis, meiosis aims for genetic diversity in its creation of haploid gametes. Dividing germ cells first begin this process in prophase I, where each chromosome—replicated in S phase—is now composed of two sister chromatids (identical copies) joined centrally.
The homologous pairs of sister chromosomes—one from the maternal and one from the paternal genome—then begin to align alongside each other lengthwise, matching corresponding DNA positions in a process...
The homologous pairs of sister chromosomes—one from the maternal and one from the paternal genome—then begin to align alongside each other lengthwise, matching corresponding DNA positions in a process...
171.9K
Crossing Over
6.5K
Crossing over is the exchange of genetic information between homologous chromosomes during prophase I of meiosis I. Genetic recombination gives rise to allelic diversity in the newly formed daughter cells. In humans, crossing over produces genetically distinct haploid egg and sperm cells that undergo fertilization to produce unique offspring. Before cell division starts, the germ cell’s chromosome(s) undergo duplication in the S phase of the cell cycle. As the cells enter prophase I,...
6.5K
Switching of BJT
857
Switching behavior in Bipolar Junction Transistors (BJTs) is a fundamental aspect utilized in various electronic circuits, particularly for digital logic applications like switches and amplifiers. In a typical switching circuit, a BJT alternates between cut-off and saturation modes, corresponding to the "off" and "on" states, respectively, thus behaving like an ideal switch.
Cut-off Mode ("Off" State): In this state, both the emitter-base and collector-base junctions are...
Cut-off Mode ("Off" State): In this state, both the emitter-base and collector-base junctions are...
857
Covalently Linked Protein Regulators
9.6K
Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
These groups modify specific amino acids in a protein....
9.6K


