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Updated: Jan 30, 2026

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
07:02

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry

Published on: August 25, 2016

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二次軌道相互作用は,ダイエルス-アルダーサイクル添加物におけるアルキンの反応性を高める

Brian J Levandowski1, Dennis Svatunek1,2, Barbara Sohr2

  • 1Department of Chemistry and Biochemistry , University of California, Los Angeles , Los Angeles , California 90095 , United States.

Journal of the American Chemical Society
|January 30, 2019
PubMed
まとめ

トランス・サイクロオクトン (TCO) とエンド・バイクロ[6.1.0]ノニン (BCN) は,逆電子需要ダイエルス・アルダー反応で異なる反応性を示す. TCOは,より高いHOMOエネルギーにより,テトラジンとより速く反応し,BCNは,二次軌道相互作用を通じて,オルトベンゾキノンとより大きな反応性を示す.

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